
The two most typical methods of crude-oil desalting,
chemical and electrostatic separation, use hot water as the extraction agent.
In chemical desalting, water and chemical surfactant
(demulsifiers) are added to the crude, heated so that salts and other impurities
dissolve into the water or attach to the water, and then held in a tank where
they settle out. Electrical desalting is the application of high-voltage
electrostatic charges to concentrate suspended water globules in the bottom of
the settling tank. Both methods of desalting are continuous.
Chem-electrical desalters combine the use of demulsifiers plus the application
of electrostatic charges.
A third and less-common process involves filtering heated
crude using diatomaceous earth. The feedstock crude oil is heated to
between 150° and 350°F to reduce viscosity and surface tension for easier
mixing and separation of the water. The temperature is limited by the vapor
pressure of the crude-oil feedstock.
In both methods other chemicals may be added. Ammonia is
often used to reduce corrosion. Caustic or acid may be added to adjust the
pH of the water wash.
Wastewater and contaminants are discharged from the bottom
of the settling tank to the wastewater treatment facility.
The desalted crude is continuously drawn from the top of
the settling tanks and sent to the crude distillation (fractionating) tower.